Family Albom

Sunday, February 8, 2009

Why benzaldehyde does not give fehlings test..?

Fehiling's solution is an alkaline solution of copper sulphate containing sodium potassium tartarate.

When Fehling's solution is added to a aldehyde, it gives out a red precipitate. This red precipitate is nothing but cupprous oxide.
Normally, when Fehling's solution is added to say, acetaldehyde, it gives acetic acid and cupprous oxide.

CH3-CHO + 2CuO -----------> CH3-COOH + Cu2O

But when benzaldehyde is added, it rapidly converts into benzyl alcohol and sodium benzoate because of the presence of alkali(Cannizzro's Reaction) . Here, there is no formation of cupprous oxide to give out a red precipitate.

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