Fehiling's solution is an alkaline solution of copper sulphate containing sodium potassium tartarate.
When Fehling's solution is added to a aldehyde, it gives out a red precipitate. This red precipitate is nothing but cupprous oxide.
Normally, when Fehling's solution is added to say, acetaldehyde, it gives acetic acid and cupprous oxide.
CH3-CHO + 2CuO -----------> CH3-COOH + Cu2O
But when benzaldehyde is added, it rapidly converts into benzyl alcohol and sodium benzoate because of the presence of alkali(Cannizzro's Reaction) . Here, there is no formation of cupprous oxide to give out a red precipitate.
Family Albom
Sunday, February 8, 2009
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